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Home / Crystal / Lenses / CVD Zinc Selenide®(ZnSe)Optical Material for IR Lasers

CVD Zinc Selenide®(ZnSe)Optical Material for IR Lasers

IdealPhotonics Chemically vapor-deposited CVD Zinc Selenide® is the material of choice for use as optical components in high-powered CO2 lasers due to its low bulk absorption at 10.6 µm. Its index of refraction homogeneity and uniformity offers excellent optical performance for use as protective windows or optical elements in high-resolution forward-looking (FLIR) thermal imaging equipment.

This material can also be used as small windows and lenses in medical and industrial applications, such as thermometry and spectroscopy.

CVD Zinc Selenide® is chemically inert, non-hygroscopic, highly pure, theoretically dense and easily machined. It has extremely low bulk losses due to absorption and scatter, has a high resistance to thermal shock and is stable in virtually all environments.

Custom diameters, rectangles, CNC-profiled blanks, generated lens blanks, prisms and near-net shape domes can be made to your specifications.

Name Price Operation
25.4mm x 500mm ZnSe Positive Lenses $299.00
25.4mm x 500mm ZnSe Positive Lenses $188.00
25.4mm x 250mm ZnSe Positive Lenses $299.00
25.4mm x 250mm ZnSe Positive Lenses $188.00
25.4mm x 195mm ZnSe Positive Lenses $299.00
25.4mm x 195mm ZnSe Positive Lenses $188.00
25.4mm x 150mm ZnSe Positive Lenses $299.00
25.4mm x 150mm ZnSe Positive Lenses $188.00
25.4mm x 65mm ZnSe Positive Lenses $299.00
25.4mm x 65mm ZnSe Positive Lenses $188.00
25.4mm x 30mm ZnSe Positive Lenses $299.00
25.4mm x 30mm ZnSe Positive Lenses $188.00
25.4mm x 25mm ZnSe Positive Lenses $188.00
13mm x 280mm ZnSe Positive Lenses $188.00
10mm x 10mm ZnSe Positive Lenses $299.00
5mm x 400mm ZnSe Positive Lenses $188.00
Features

● Excellent transmittance in IR (up to 20µm)

● Chemically inert

● High resistance to thermal and environmental impacts

● Non-hygroscopic

● Easy to machine

Physical/Optical Characteristics

Transmission Range :

0.6 to 21.0 μm

Refractive Index :

2.4028 at 10.6 μm

Reflection Loss :

29.1% at 10.6 μm (2 surfaces)

Absorption Coefficient :

0.0005 cm-1 at 10.6 μm

Reststrahlen Peak :

45.7 μm

dn/dT :

+61 x   10-6/°C at 10.6 μm at 298K

dn/dμ = 0 :

5.5 μm

Density :

5.27   g/cc

Melting Point :

1525°C (see notes below)

Thermal Conductivity :

18 W m-1 K-1 at 298K

Thermal Expansion :

7.1 x 10-6 /°C at 273K

Hardness :

Knoop 120 with 50g indenter

Specific Heat Capacity :

339J Kg-1 K-1

Dielectric Constant :

n/a

Youngs Modulus (E) :

67.2 GPa

Shear Modulus (G) :

n/a

Bulk Modulus (K) :

40 GPa

Elastic Coefficients :

Not Available

Apparent Elastic Limit :

55.1 MPa (8000 psi)

Poisson Ratio :

0.28

Solubility :

0.001g/100g water

Molecular Weight :

144.33

Class/Structure :

FCC   Cubic, F43m (#216), Zinc Blende structure. (Polycrystalline)


µm

No

µm

No

µm

No

0.54

2.6754

0.58

2.6312

0.62

2.5994

0.66

2.5755

0.7

2.5568

0.74

2.5418

0.78

2.5295

0.82

2.5193

0.86

2.5107

0.90

2.5034

0.94

2.4971

0.98

2.4916

1.0

2.4892

1.4

2.4609

1.8

2.4496

2.2

2.4437

2.6

2.4401

3.0

2.4376

3.4

2.4356

3.8

2.4339

4.2

2.4324

4.6

2.4309

5.0

2.4295

5.4

2.4281

5.8

2.4266

6.2

2.4251

6.6

2.4235

7.0

2.4218

7.4

2.4201

7.8

2.4183

8.2

2.4163

8.6

2.4143

9.0

2.4122

9.4

2.4100

9.8

2.4077

10.2

2.4053

10.6

2.4028

11.0

2.4001

11.4

2.3974

11.8

2.3945

12.2

2.3915

12.6

2.3883

13.0

2.3850

13.4

2.3816

13.8

2.3781

14.2

2.3744

14.6

2.3705

15.0

2.3665

15.4

2.3623

15.8

2.3579

16.2

2.3534

16.6

2.3487

17.0

2.3438

17.4

2.3387

17.8

2.3333

18.2

2.3278



No = Ordinary Ray

Zinc Selenide is produced by synthesis from Zinc vapour and H2Se gas, forming as sheets on Graphite susceptors. Zinc Selenide is microcrystalline in structure, the grain size being controlled to produce maximum strength. Single crystal ZnSe is available, but is not common but has been reported as having lower absorption and thus more effective for CO2 optics.

Spectral Transmission CVD Zinc Selenide® 

ZnSe1.png

Application

BaF2 is an excellent optical material for a broad spectral range in VIS and IR. This enables utilization in sophisticated applications:

● Thermal imaging and night vision with integrated VIS channel

● Optics for astronomical instrumentation

● Infrared laser optics

● Scintillator for the detection of high energy γ-radiation >5Me